MICROWAVE-SPECTRUM AND STRUCTURE OF THE GT ISOMER OF CHLOROMETHYLETHYL ETHER

被引：15

作者：

HAYASHI, M

KATO, H

机构：

[1] Department of Chemistry, Faculty of Science, Hiroshima University, Hiroshima, 730, Higashi-sendamachi

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1979年 / 53卷 / 02期

关键词：

D O I：

10.1016/0022-2860(79)80340-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Microwave spectra of chloromethylethyl ether and its thirteen isotopically substituted species have been measured. The rs structure of the GT isomer of this molecule was determined from the observed moments of inertia. It is noted that one of the two CH bonds in the OCH2C group gives a remarkably large value (1.225 Å). This anomalous bond is nearly parallel to the CCl bond in the molecule. In order to ascertain this anomaly, measurements of spectral intensities and microwave double resonance experiments have been carried out for the species relating to this CH bond. © 1979.

引用

页码：179 / 188

页数：10

共 8 条

[1] MICROWAVE-SPECTRUM, STRUCTURE AND DIPOLE-MOMENT OF ETHANETHIOL .1. TRANS ISOMER [J].