Reactions of oxygen atoms, part II. Relative rate data for the quenching of O(2(1)D(2)) using the OH radical as a spectroscopic marker

被引：29

作者：

Donovan, R. J. ^{[1
]}

Husain, D. ^{[1
]}

Kirsch, L. J. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Phys Chem, Cambridge, England

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 6卷 / 05期

关键词：

D O I：

10.1016/0009-2614(70)85200-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

OH radicals, resulting from exothermic hydrogen atom abstraction reactions of O(2(1)D2). generated by the flash photolysis of NO2 and of N2O. with hydride molecules. have been monitored by kinetic absorption spectroscopy in the ultraviolet. The variation in the spectral intensity of OH( A(2)Sigma(+)<- X-2 Pi) in the presence of added gases has yielded relative quenching data for O(2(1)D(2)) with the species Kr, Xe, H-2. N-2, CO2, N2O ard CH4.

引用

页码：488 / 490

页数：3

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