MAGNETIC AND SPECTRAL PROPERTIES OF PARAMAGNETIC METAL-ION POLYOXOLENE RADICAL COMPLEXES

被引：50

作者：

DEI, A ^{[1
]}

GATTESCHI, D ^{[1
]}

机构：

[1] UNIV FLORENCE, DEPT CHEM, I-50121 FLORENCE, ITALY

来源：

INORGANICA CHIMICA ACTA | 1992年 / 198卷

关键词：

D O I：

10.1016/S0020-1693(00)92427-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The magnetic properties of complexes containing paramagnetic metal ions bound to polyoxolene radicals are reviewed. First we report simple 1:1 complexes which provide useful criteria for the magnetic exchange involving radicals and metal ions. The second section is devoted to the magnetic properties and EPR spectra of metal-polyoxolene complexes of varying complexities. The complexes are collected according to the metal ion. Finally we report the optical properties of the complexes, particular attention being devoted to the interplay of optical and magnetic properties.

引用

页码：813 / 822

页数：10

共 52 条

[1] Anderson P. W., 1963, MAGNETISM, V1, P25
[2] Bencini A., 1990, EPR EXCHANGE COUPLED
[3] REDOX POTENTIALS AND CHARGE-TRANSFER SPECTRA OF CATECHOLATE AND SEMIQUINONE ADDUCTS OF A COBALT TETRAAZAMACROCYCLIC COMPLEX
BENELLI, C
DEI, A
GATTESCHI, D
PARDI, L
[J]. INORGANICA CHIMICA ACTA, 1989, 163 (01) : 99 - 104
[4] ELECTRONIC-STRUCTURE AND REACTIVITY OF DIOXOLENE ADDUCTS OF NICKEL(II) AND COPPER(II) TRIAZAMACROCYCLIC COMPLEXES
BENELLI, C
DEI, A
GATTESCHI, D
PARDI, L
[J]. INORGANIC CHEMISTRY, 1990, 29 (18) : 3409 - 3415
[5] SYNTHESIS, REDOX BEHAVIOR, MAGNETIC-PROPERTIES, AND CRYSTAL-STRUCTURE OF A NICKEL(II)-SEMIQUINONE ADDUCT WITH AN UNUSUALLY STRONG FERROMAGNETIC COUPLING
BENELLI, C
DEI, A
GATTESCHI, D
PARDI, L
[J]. INORGANIC CHEMISTRY, 1988, 27 (16) : 2831 - 2836
[6] INTERNAL ELECTRON-TRANSFER IN A QUINONE ADDUCT OF A NICKEL(II)-CATECHOLATE COMPLEX
BENELLI, C
DEI, A
GATTESCHI, D
PARDI, L
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (20) : 6897 - 6898
[7] LARGE INTENSITY ENHANCEMENT OF THE SPIN-FORBIDDEN 4A2G-]2EG TRANSITION IN CHROMIUM(III) SEMIQUINONE COMPLEXES
BENELLI, C
DEI, A
GATTESCHI, D
GUDEL, HU
PARDI, L
[J]. INORGANIC CHEMISTRY, 1989, 28 (16) : 3089 - 3091
[8] ELECTRONIC AND CD SPECTRA OF CATECHOLATE AND SEMIQUINONATE ADDUCTS OF ZINC(II) AND NICKEL(II) TETRAAZA MACROCYCLIC COMPLEXES
BENELLI, C
DEI, A
GATTESCHI, D
PARDI, L
[J]. INORGANIC CHEMISTRY, 1989, 28 (08) : 1476 - 1480
[9] MAGNETIC EXCHANGE INTERACTIONS IN SEMIQUINONE COMPLEXES OF IRON - STRUCTURAL AND MAGNETIC-PROPERTIES OF TRIS(3,5-DI-TERT-BUTYLSEMIQUINONATO)IRON(III) AND TETRAKIS(3,5-DI-TERT-BUTYLSEMIQUINONATO)TETRAKIS(3,5-DI-TERT-BUTYLCATECHOLATO)TETRAIRON(III)
BOONE, SR
PURSER, GH
CHANG, HR
LOWERY, MD
HENDRICKSON, DN
PIERPONT, CG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (06) : 2292 - 2299
[10] INTRA-MOLECULAR ANTI-FERROMAGNETIC EXCHANGE IN TRIS(ORTHO-SEMIQUINONE)COMPLEXES OF VANADIUM(III), CHROMIUM(III), AND IRON(III)
BUCHANAN, RM
DOWNS, HH
SHORTHILL, WB
PIERPONT, CG
KESSEL, SL
HENDRICKSON, DN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (13) : 4318 - 4320

← 1 2 3 4 5 6 →