HIGHLY RESOLVED ELECTRON-PARAMAGNETIC RESONANCE-SPECTRUM OF COPPER(II) ION-PAIRS IN CUCE OXIDE

被引：75

作者：

ABOUKAIS, A ^{[1
]}

BENNANI, A ^{[1
]}

AISSI, CF ^{[1
]}

WROBEL, G ^{[1
]}

GUELTON, M ^{[1
]}

VEDRINE, JC ^{[1
]}

机构：

[1] INST RECH CATALYSE,CNRS,F-69626 VILLEURBANNE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1992年 / 88卷 / 04期

关键词：

D O I：

10.1039/ft9928800615

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A copper-cerium oxide sample prepared with an atomic ratio, Cu:Ce, of 0.01 has been studied by electron paramagnetic resonance (EPR) spectroscopy. A well resolved spectrum of copper(II) ion pairs has been evidenced and the hyperfine structure of the perpendicular components clearly appears. The high resolution can be explained by the presence of two nearly equivalent Cu2+ ions separated by an oxygen ion. A correlation in EPR parameters has been found between the signal corresponding to a single Cu2+ ion, a precursor of the dimer, and the copper(II) ion pair spectrum.

引用

页码：615 / 620

页数：6

共 40 条

[1] ABOUKAIS A, 1991, CR ACAD SCI II, V313, P169
[2] TEMPERATURE BEHAVIOR OF AN ESR COPPER(II) ION-PAIRS SPECTRUM FORMED BY 2 NONEQUIVALENT CU2+ IONS
ABOUKAIS, A
BECHARA, R
AISSI, CF
GUELTON, M
[J]. CHEMISTRY OF MATERIALS, 1991, 3 (03) : 557 - 559
[3] ABOUKAIS A, 1991, J CHEM SOC FARADAY T, V87, P631
[4] ABOUKAIS A, UNPUB J CHEM SOC FAR
[5] Abragam A., 1970, ELECT PARAMAGNETIC R
[6] DETECTION OF ISOLATED AND PAIRED CU-2+ IONS IN NAFION MEMBRANES BY ELECTRON-SPIN-RESONANCE SPECTROSCOPY
ALONSOAMIGO, MG
SCHLICK, S
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (23) : 6353 - 6358
[7] AMARA M, 1988, APPL CATAL, V41, P141
[8] MAGNETIC PROPERTIES OF POLYNUCLEAR TRANSITION METAL COMPLEXES
BALL, PW
[J]. COORDINATION CHEMISTRY REVIEWS, 1969, 4 (03) : 361 - &
[9] PREPARATION AND CHARACTERIZATION OF COPPER-THORIUM OXIDE CATALYSTS .1. SOLID-SOLUTION OF COPPER(II) IN THORIA - AN ESR STUDY
BECHARA, R
WROBEL, G
AISSI, CF
GUELTON, M
BONNELLE, JP
ABOUKAIS, A
[J]. CHEMISTRY OF MATERIALS, 1990, 2 (05) : 518 - 522
[10] PREPARATION AND CHARACTERIZATION OF COPPER THORIUM-OXIDE CATALYSTS .2. ESR STUDY OF COPPER(II) ION-PAIRS AND CORRELATION WITH THE SELECTIVE HYDROGENATION OF ISOPRENE
BECHARA, R
DHUYSSER, A
AISSI, CF
GUELTON, M
BONNELLE, JP
ABOUKAIS, A
[J]. CHEMISTRY OF MATERIALS, 1990, 2 (05) : 522 - 526

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