PHOSPHORANE IMINATO COMPLEXES OF MANGANESE AND COBALT WITH HETEROCUBANE STRUCTURE

被引：45

作者：

MAI, HJ ^{[1
]}

KOCKER, RMZ ^{[1
]}

WOCADLO, S ^{[1
]}

MASSA, W ^{[1
]}

DEHNICKE, K ^{[1
]}

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 11期

关键词：

COBALT COMPOUNDS; HETEROCUBANES; MANGANESE COMPOUNDS; PHOSPHORANE IMINATO COMPLEXES;

D O I：

10.1002/anie.199512351

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mn4N4 and Co4N4 cubes with almost square faces are found in the title compounds 1 and 2. They were obtained by the melt reaction of the anhydrous dihalides MnI2 and CoCl2, and Me3SiNPEt3. Complexes 1 and 2 are the first phosphorane iminato complexes of manganese(II) and cobalt(II) with heterocubane structure. (Formula Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：1235 / 1236

页数：2

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