STRUCTURE AND CHEMISTRY OF THE ALDEHYDE AMMONIAS .3. FORMALDEHYDE-AMMONIA REACTION - 1,3,5-HEXAHYDROTRIAZINE

被引：73

作者：

NIELSEN, AT

MOORE, DW

OGAN, MD

ATKINS, RL

机构：

[1] Chemistry Division, Research Department, Code 385, Naval Weapons Center, California, China Lake

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 10期

关键词：

D O I：

10.1021/jo01324a021

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The formaldehyde-ammonia reaction has been examined in D2O solvent with the aid of 1H and13C NMR spectroscopy. Reaction intermediates, including 1, 3, 5-hexahydrotriazine (2) and l, 3, 5, 7-tetraazabicyclo[3.3.1]nonane(6), are observed, and the mechanisms of their formation and conversion into hexamine are discussed. Solutions previously reported to contain 2 alone have been shown to be complex mixtures. © 1979, American Chemical Society. All rights reserved.

引用

页码：1678 / 1684

页数：7

共 45 条

[1] EQUILIBRIA AND KINETICS OF N-HYDROXYMETHYLAMINE FORMATION FROM AROMATIC EXOCYCLIC AMINES AND FORMALDEHYDE - EFFECTS OF NUCLEOPHILICITY AND CATALYST STRENGTH UPON MECHANISMS OF CATALYSIS OF CARBINOLAMINE FORMATION [J].