ELECTROCHEMICAL POLYMERIZATION OF N-VINYLCARBAZOLE

被引：11

作者：

BHADANI, SN

机构：

[1] Department of Chemistry, Ranchi University, Ranchi

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1991年 / 42卷 / 05期

关键词：

D O I：

10.1002/app.1991.070420509

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The electrolysis of N-vinylcarbazole in the solution of quaternary ammonium salts in dichloroethane leads to polymer formation in the anolyte. The effect of monomer concentrations, current levels, and nature of supporting electrolytes on the polymerization has been investigated. The polymerization is free radical with bromide salt and cationic with perchlorate or hexachloroantimonate salt. The poly(N-vinylcarbazole) gets oxidized at the anode and can be cycled between the oxidized and neutral states. The oxidized polymers at the electrode may exhibit electrical conductivity.

引用

页码：1271 / 1273

页数：3

共 18 条

[1]

BHADANI SN, 1976, MAKROMOL CHEM, V177, P907

[2]

BHADANI SN, 1974, T SOC ADV ELECTROCHE, V9, P170

[3]

BISWAS M, 1982, POLYMER, V23, P1713, DOI 10.1016/0032-3861(82)90112-4

[4]

Bloor D., 1989, COMPREHENSIVE POLYM, V2, P687