SYNTHESIS AND MOLECULAR-STRUCTURE OF MONOMERIC COPPER(II) ACETATES WITH 2-METHYLIMIDAZOLE AND 1,2-DIMETHYLIMIDAZOLE

被引：66

作者：

ABUHIJLEH, AL

WOODS, C

AHMED, IY

机构：

[1] UNIV TENNESSEE,DEPT CHEM,KNOXVILLE,TN 37996

[2] BIR ZEIT UNIV,DEPT CHEM,W BANK,ISRAEL

[3] UNIV MISSISSIPPI,DEPT CHEM,UNIVERSITY,MS 38677

来源：

INORGANICA CHIMICA ACTA | 1991年 / 190卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)80226-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes cis-bis(acetato)bis(2-methylimidazole)copper(II) (1), and cis-bis(acetato)bis(1,2-dimethylimidazole)copper(II) (2) have been prepared by the reaction of the appropriate imidazole derivative with copper(II) tetraacetate. The complexes have been characterized by analytical, magnetic, spectroscopic and crystallographic methods. Complex 1 crystallizes in the orthorhombic space group P2(1)2(1)2(1) and has unit cell dimensions of a = 7.5380(10), b = 7.7100(10), c = 26.310(5) angstrom. Complex 2 crystallizes in the monoclinic space group P2/c and has unit cell dimensions of a = 15.574(2), b = 7.9520(10), c = 14.752(2) angstrom.

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页码：11 / 17

页数：7

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