CHEMICAL KINETIC DATA SHEETS FOR HIGH-TEMPERATURE REACTIONS .2.

被引:180
作者
COHEN, N
WESTBERG, KR
机构
[1] Space and Environment Technology Center, The Aerospace Corporation, Los Angeles
关键词
ATMOSPHERIC CHEMISTRY; CHEMICAL REACTION KINETICS; COMBUSTION; COMPILED DATA; HIGH TEMPERATURE; PROPULSION; ULTRAHIGH TEMPERATURE; VERY HIGH TEMPERATURE;
D O I
10.1063/1.555901
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Rate coefficient measurements for over fifty gas-phase bimolecular reactions were critically evaluated and compared to theoretical calculations. The results of this work are summarized here in forty-nine Data Sheets, one sheet for each reaction or set of reactions of a single pair of reagents. The reactions chosen are of interest in propulsion, combustion, and atmospheric chemistry. Each Data Sheet consists of two pages that include a brief resume of the important experimental measurements and theoretical calculations, a graphical presentation of the data, a recommended rate coefficient expressed as a function of temperature, k(T) = AT(n)exp(-B/T), with probable uncertainty limits, a discussion of the basis for the recommendation, an equilibrium constant and a rate coefficient for the reverse reaction where applicable, and pertinent references.
引用
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页码:1211 / 1311
页数:101
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