ADDITION OF TETRACHLOROMETHANE TO ALKENES CATALYZED BY COBALT(II) AMINE COMPLEX

被引：13

作者：

KOTORA, M ^{[1
]}

ADAMEK, F ^{[1
]}

HAJEK, M ^{[1
]}

机构：

[1] CZECHOSLOVAK ACAD SCI, INST CHEM PROC FUNDAMENTALS, ROZVOJOVA 135, CS-16502 PRAGUE 6, CZECHOSLOVAKIA

来源：

CATALYSIS LETTERS | 1993年 / 18卷 / 04期

关键词：

ADDITION REACTIONS; COBALT(II) CATALYST; FREE RADICALS;

D O I：

10.1007/BF00765280

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The cobalt(II)-2-methylpropylamine complex is an efficient catalyst for addition of tetrachloromethane to alkenes under mild reaction conditions (80-degrees-C) providing 1 : 1 adducts up to 99.5% yield. Reactions with vinyl monomers provided low yield of 1 : 1 addition products (5-48%) presumably due to radical chain processes favoring telomerization and polymerization.

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页码：345 / 348

页数：4

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