SOLVOLYSIS OF FURYLMETHYLCARBINOL DERIVATIVES

被引：54

作者：

NOYCE, DS

KAISER, GV

机构：

[1] Department of Chemistry, University of California at Berkeley, Berkeley

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 04期

关键词：

D O I：

10.1021/jo01256a053

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A kinetic study of the solvolysis of a series of furylmethylearbinyl p-nitrobenzoates has been carried out. Substituents in the 5 position exert a profound influence on the rate of solvolysis. Results for six different substituents are satisfactorily correlated by Brown's σ+ substituent constants with ρ -7.5, one of the most negative values for ρ observed in the correlation of solvolysis reactions. © 1969, American Chemical Society. All rights reserved.

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页码：1008 / &

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