AMBIDENT NUCLEOPHILICITY OF SULFENATE ANIONS

被引：19

作者：

HOGG, DR

ROBERTSON, A

机构：

[1] Department of Chemistry, University of Aberdeen

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 04期

关键词：

D O I：

10.1039/p19790001125

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Nitro-4-trifluoromethylbenzene- and 2-nitrobenzene-sulphenate anions, generated by the base-catalysed hydrolysis of the corresponding disulphide or sulphenate ester, undergo S-methylation with methyl iodide but predominantly O-methylation with the 'harder' methylating agents, methyl fluorosulphonate and dimethyl sulphate. Sulphinate ions react similarly with methyl fluorosulphonate.

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页码：1125 / 1128

页数：4

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