PHOTODISSOCIATION OF ICL MOLECULES ORIENTED IN AN ELECTRIC-FIELD - DIRECT DETERMINATION OF THE SIGN OF THE DIPOLE-MOMENT

被引：12

作者：

BAZALGETTE, G ^{[1
]}

WHITE, R ^{[1
]}

LOISON, JC ^{[1
]}

TRENEC, G ^{[1
]}

VIGUE, J ^{[1
]}

机构：

[1] CNRS,URA 770,F-31062 TOULOUSE,FRANCE

来源：

CHEMICAL PHYSICS LETTERS | 1995年 / 244卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(95)00970-F

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have used the 'brute force' technique of Loesch to orient strongly a molecular beam of ICl, and we have measured directly the orientation by a photodissociation experiment. This experiment gives also a direct access to the sign of the dipole moment of ICl in its X (1) Sigma(+) state, which is found to be I+Cl-.

引用

页码：195 / 198

页数：4

共 15 条

[1] DETERMINATION OF MOLECULAR-ORIENTATION AND ALIGNMENT FROM POLARIZED LASER PHOTOFRAGMENTATION MEASUREMENTS - ORIENTED CH3I MOLECULAR-BEAMS
BERNSTEIN, RB
CHOI, SE
STOLTE, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1989, 85 : 1097 - 1113
[2] CURVE CROSSING AND REPULSIVE POTENTIALS PROBED BY LASER-INDUCED HALF COLLISIONS - IC1 AND IBR
DEVRIES, MS
VANVEEN, NJA
HUTCHINSON, M
DEVRIES, AE
[J]. CHEMICAL PHYSICS, 1980, 51 (1-2) : 159 - 168
[3] LASER SPECTROSCOPY OF SUPERSONIC EXPANSIONS OF ICL
HANSEN, SG
THOMPSON, JD
KENNEDY, RA
HOWARD, BJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1982, 78 : 1293 - 1310
[4] SUPERCOOLED MOLECULES IN MOLECULAR-BEAMS OF ICI AND IBR
KEIL, D
LUBBERT, A
SCHUGERL, K
[J]. JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (08) : 3845 - 3850
[5] ENERGY-LEVELS OF IODINE MONOCHLORIDE NEAR 1ST DISSOCIATION LIMIT
KING, GW
MCFADDEN, RG
[J]. CHEMICAL PHYSICS LETTERS, 1978, 58 (01) : 119 - 121
[6] REACTIVE SCATTERING OF K FROM ORIENTED AND ISOTROPIC CH3I MOLECULES
LOESCH, HJ
REMSCHEID, A
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (21) : 8194 - 8200
[7] BRUTE FORCE IN MOLECULAR REACTION DYNAMICS - A NOVEL TECHNIQUE FOR MEASURING STERIC EFFECTS
LOESCH, HJ
REMSCHEID, A
[J]. JOURNAL OF CHEMICAL PHYSICS, 1990, 93 (07) : 4779 - 4790
[8] LOISON JC, UNPUB
[9] LOISON JC, IN PRESS J PHYS CHEM
[10] LUBBERT A, 1978, J CHEM PHYS, V69, P5174, DOI 10.1063/1.436464

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