PHOTOCHEMISTRY OF TRANSITION-METAL HYDRIDES AND DIHYDROGEN COMPLEXES - THEORETICAL ASPECTS

被引：11

作者：

VEILLARD, A

机构：

[1] UPR 139 du CNRS, Institut Le Bel, 6700 Strasbourg

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 170卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(90)87081-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The mechanism of the photochemical reactions of transition-metal hydrides and dihydrogen complexes is discussed on the basis of recently published potential-energy curves and qualitative energy-level diagrams. © 1990.

引用

页码：441 / 445

页数：5

共 35 条

[1] 8-COORDINATION [J].

BURDETT, JK ;

HOFFMANN, R ;

FAY, RC .

INORGANIC CHEMISTRY, 1978, 17 (09) :2553-2568

[2] ELECTRONIC STABILITY OF METAL DIHYDROGEN AND METAL-POLYHYDROGEN COMPLEXES [J].

BURDETT, JK ;

PHILLIPS, JR ;

POURIAN, MR ;

POLIAKOFF, M ;

TURNER, JJ ;

UPMACIS, R .

INORGANIC CHEMISTRY, 1987, 26 (18) :3054-3063

[3] PHOTOCHEMICAL-REACTIONS OF W(ETA-C5H5)2LN, MO(ETA-C5H5)2LN, CR-(ETA-C5H5)2LN, V(ETA-C5H5)2LN IN LOW-TEMPERATURE MATRICES - DETECTION OF TUNGSTENOCENE AND MOLYBDENOCENE [J].

CHETWYNDTALBOT, J ;

GREBENIK, P ;

PERUTZ, RN .

INORGANIC CHEMISTRY, 1982, 21 (10) :3647-3657

[4] PHOTOCHEMISTRY OF MATRIX-ISOLATED HMN(CO)5 - EVIDENCE FOR 2 ISOMERS OF HMN(CO)4 [J].

CHURCH, SP ;

POLIAKOFF, M ;

TIMNEY, JA ;

TURNER, JJ .

INORGANIC CHEMISTRY, 1983, 22 (22) :3259-3266

[5]

Cotton FA., 1988, ADV INORG CHEM, V5

[6] ELECTRONIC-STRUCTURE OF MOLYBDENOCENE AND TUNGSTENOCENE - DETECTION OF PARAMAGNETISM BY MAGNETIC CIRCULAR-DICHROISM IN ARGON MATRICES [J].

COX, PA ;

GREBENIK, P ;

PERUTZ, RN ;

ROBINSON, MD ;

GRINTER, R ;

STERN, DR .

INORGANIC CHEMISTRY, 1983, 22 (24) :3614-3620

[7] ORGANOMETALLIC PHOTOCHEMISTRY - ABINITIO POTENTIAL-ENERGY SURFACES AS REACTION MAPS OF THE PRIMARY PHOTOPROCESS [J].

DANIEL, C .

COORDINATION CHEMISTRY REVIEWS, 1990, 97 :141-154

[8]

DANIEL C, UNPUB

[9] MOLECULAR-ORBITAL ANALYSIS OF THE OXIDATIVE ADDITION OF HYDROGEN TO THE CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) COMPLEX [J].

DEDIEU, A ;

STRICH, A .

INORGANIC CHEMISTRY, 1979, 18 (10) :2940-2943

[10]

Geoffroy G.L., 1979, ORGANOMETALLIC PHOTO

← 1 2 3 4 →