C-13 NMR-SPECTRA OF PI-ARENECHROMIUM CARBONYL-COMPLEXES

被引：20

作者：

FEDOROV, LA

PETROVSKII, PV

FEDIN, EI

PANOSYAN, GA

TSOI, AA

BARANETSKAYA, NK

SETKINA, VN

机构：

[1] Institute of Organo-Element Compounds, Academy of Sciences, the U.S.S.R., Moscow, N-312

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 182卷 / 04期

关键词：

D O I：

10.1016/S0022-328X(00)83939-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 13C NMR spectra of π-arenechromium complexes XC6H5Cr(CO)2L (where I, L CO; II, L PPh3; X aliphatic and aromatic substituents) were investigated. The effect of the nature of the substituent X on the chemical shifts of the carbon atoms of the aromatic ring in these complexes was analyzed. It was established that a correlation exists between δ(13C) and σR (Taft's constant) in complexes I, not only for C(4) nuclei but also for C(3) metal atoms, the difference being that the slopes of the corresponding curves are opposite. © 1979.

引用

页码：499 / 510

页数：12

共 30 条

[1] BASE-CATALYZED DEUTERATION OF TRICARBONYLCHROMIUM COMPLEXES
ASHRAF, M
[J]. CANADIAN JOURNAL OF CHEMISTRY, 1972, 50 (01): : 118 - &
[2] BARANETSKAYA NK, 1975, IZV AKAD NAUK SSSR K, V7, P1494
[3] FOURIER-TRANSFORM C-13 NUCLEAR MAGNETIC-RESONANCE STUDY OF (ARENE)TRICARBONYLCHROMIUM COMPLEXES
BODNER, GM
TODD, LJ
[J]. INORGANIC CHEMISTRY, 1974, 13 (02) : 360 - 363
[4] FOURIER-TRANSFORM C-13 NUCLEAR MAGNETIC-RESONANCE STUDY OF TRANSITION-METAL CARBONYL-COMPLEXES
BODNER, GM
TODD, LJ
[J]. INORGANIC CHEMISTRY, 1974, 13 (06) : 1335 - 1338
[5] C-13 NMR-STUDY OF SUBSTITUTED BIPHENYL-METHANE-TRICARBONYLCHROMIUM AND DIPHENYL-METHANE-TRICARBONYLCHROMIUM "DIPHENYLETHANE-TRICARBONYLCHROMIUM, CIS-STILBENE-TRICARBONYLCHROMIUM AND BENZOPHENONE-TRICARBONYLCHROMIUM COMPLEXES
BROWN, DA
FITZPATRICK, NJ
KING, IJ
MATHEWS, NJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 104 (01) : C9 - C11
[6] THE RELATIVE RATE AND ISOMER DISTRIBUTION IN THE ACETYLATION OF BENZENE AND TOLUENE IN ETHYLENE DICHLORIDE UNDER THE INFLUENCE OF ALUMINUM CHLORIDE
BROWN, HC
MARINO, G
STOCK, LM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (13) : 3310 - 3314
[7] FEDOROV LA, 1973, DOKL AKAD NAUK SSSR+, V209, P404
[8] MOLECULAR-ORBITAL THEORY OF ELECTRONIC-STRUCTURE OF ORGANIC COMPOUNDS .12. CONFORMATIONS, STABILITIES, AND CHARGE DISTRIBUTIONS IN MONOSUBSTITUTED BENZENES
HEHRE, WJ
POPLE, JA
RANDOM, L
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (05) : 1496 - &
[9] UBER AROMATENKOMPLEXE VON METALLEN .65. DIE ISOMERENVERTEILUNG BEI DER FRIEDEL-CRAFTS-ACETYLIERUNG DES PI-TOLUOL-CHROM-TRICARBONYLS UND DES FREIEN TOLUOLS
HERBERICH, GE
FISCHER, EO
[J]. CHEMISCHE BERICHTE-RECUEIL, 1962, 95 (11): : 2803 - &
[10] INAMOTO N, 1976, TETRAHEDRON LETT, P3707

← 1 2 3 →