A STUDY OF THE INFLUENCE OF PARTICLE-SIZE ON THE THERMAL-DECOMPOSITION OF CACO3 BY MEANS OF CONSTANT RATE THERMAL-ANALYSIS

被引:61
作者
CRIADO, JM [1 ]
ORTEGA, A [1 ]
机构
[1] UNIV SEVILLE,CSIC,CTR MIXTO,DEPT QUIM INORGAN,SEVILLE,SPAIN
关键词
D O I
10.1016/0040-6031(92)80059-6
中图分类号
O414.1 [热力学];
学科分类号
摘要
The influence of particle size on the kinetic parameters of the thermal decomposition of calcite is investigated. The new constant rate thermal analysis (CRTA) technique which allows considerably better control of the heat and mass transfer phenomena has been used. It is found that the activation energy of the thermal decomposition of calcite smoothly increases by increasing the particle size.
引用
收藏
页码:163 / 167
页数:5
相关论文
共 6 条
[1]   STUDY OF THE THERMAL-DECOMPOSITION REACTION-MECHANISM OF ALKALINE-EARTH CARBONATES UNDER HIGH-VACUUM BY BOTH THERMOGRAVIMETRIC ANALYSIS AND CONSTANT DECOMPOSITION RATE THERMAL-ANALYSIS TECHNIQUES [J].
CRIADO, JM ;
ROUQUEROL, F ;
ROUQUEROL, J .
THERMOCHIMICA ACTA, 1980, 38 (01) :117-123
[2]  
CRIADO JM, 1978, B SOC ESP CERAM VIDR, V17, P23
[3]  
Gallagher P.K., 1973, THERMOCHIM ACTA, V6, P67, DOI 10.1016/0040-6031(73)80007-3
[4]  
ROUQUEROL J, 1964, B SOC CHIM FR, P31
[5]  
ROUQUEROL J, 1976, J THERM ANAL, V5, P273
[6]  
Webb TL., 1970, DIFFERENTIAL THERMAL, P303