GAS-PHASE REACTIONS .81. FPS2 AND FPS

被引：10

作者：

BOCK, H

KREMER, M

SOLOUKI, B

BINNEWIES, M

MEISEL, M

机构：

[1] UNIV FREIBURG,INST INORGAN CHEM,W-7800 FREIBURG,GERMANY

[2] ACAD SCI BERLIN,O-1199 BERLIN,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 01期

关键词：

D O I：

10.1039/c39920000009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The pyridinium betaine H5C5N.FPS2 dissociates at 770 K in the gas phase yielding the novel sigma(3)lambda(5)-phosphorane FPS2, which at 900 K splits off S2 to give FPS as substantiated by comparison with the photoelectron spectrum from its generation by Br2FPS debromination on silver wool above 800 K.

引用

页码：9 / 11

页数：3

共 24 条

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