Vibronic and spin-orbit coupling effects in the magnetic circular dichroism of nickel(II) bromate hexahydrate

被引：8

作者：

Harding, M. J. ^{[1
]}

Mason, S. F. ^{[1
]}

Robbins, D. J. ^{[1
]}

Thomson, A. J. ^{[1
]}

机构：

[1] Univ E Anglia, Sch Chem Sci, Norwich NR4 7TJ, Norfolk, England

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 7卷 / 01期

关键词：

D O I：

10.1016/0009-2614(70)80251-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The single-crystal magnetic circular dichroism spectrum of [Ni(H2O)(6)](BrO3)(2) is found to be strongly temperature dependent with an extensive vibronic structure in the 'red' band. The main features of the spectrum consist of C terms exhibiting first- and second-order spin-orbit splitting and progressions in the nickel-oxygen stretching mode built upon a double false origin.

引用

页码：70 / 72

页数：3

共 17 条

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