UNEXPECTED REACTIVITY OF BIFUNCTIONAL HEXACOORDINATED SILICON SPECIES

被引：26

作者：

BRELIERE, C ^{[1
]}

CORRIU, RJP ^{[1
]}

ROYO, G ^{[1
]}

MAN, WWCWC ^{[1
]}

ZWECKER, J ^{[1
]}

机构：

[1] UNIV MONTPELLIER 2,HETEROCHIM & AMINOACIDES LAB,CNRS,UA 1097,PL E BATAILLON,F-34095 MONTPELLIER 05,FRANCE

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 10期

关键词：

D O I：

10.1021/om00160a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The basic transformations of SiF, SiCI, and SiH in hexacoordinated silicon species are completely different from those observed with the corresponding tetra- and pentacoordinate compounds. © 1990, American Chemical Society. All rights reserved.

引用

页码：2633 / 2635

页数：3

共 32 条

[1] REACTIVITY OF HYPERVALENT SPECIES OF SILICON - REDUCTION OF CO2 TO FORMALDEHYDE WITH FORMATION OF SILANONE
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[3] BASSINDALE AR, 1990, 23RD ORG S MIDL
[4] A GENERAL-ROUTE TO 5-COORDINATE HYDRIDOSILICATES
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[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 359 (02) : C33 - C35
[5] BECKER B, 1989, J ORGANOMET CHEM, V369, pC25
[6] REACTIVITY OF DIANIONIC HEXACOORDINATED SILICON COMPLEXES TOWARD NUCLEOPHILES - A NEW ROUTE TO ORGANOSILANES FROM SILICA
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[J]. ORGANOMETALLICS, 1988, 7 (05) : 1165 - 1171
[7] REACTION OF GRIGNARD-REAGENTS WITH DIANIONIC HEXACOORDINATED SILICON COMPLEXES - ORGANOSILICON COMPOUNDS FROM SILICA-GEL
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[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (05): : 474 - 476
[8] ENHANCEMENT OF SI-H BOND REACTIVITY IN PENTACOORDINATED STRUCTURES
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KPOTON, A
POIRIER, M
ROYO, G
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 311 (03) : C39 - C43
[9] HEXACOORDINATED SILICON SPECIES - A POSSIBLE MODEL FOR REACTION INTERMEDIATES .1. X-RAY DETERMINATION OF THE GEOMETRY IN THE SOLID-STATE
BRELIERE, C
CARRE, F
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[J]. ORGANOMETALLICS, 1989, 8 (07) : 1831 - 1833
[10] BRELIERE C, 1981, J ORGANOMET CHEM, V205, pC1, DOI 10.1016/S0022-328X(00)82945-9

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