MECHANISM OF HYDROGENATION OF NITRIC-OXIDE ON PLATINUM CATALYSTS IN ACIDIC SOLUTION

被引：6

作者：

PASEKA, I

机构：

[1] Institute of Inorganic Chemistry, Czechoslovak Academy of Sciences, Prague 6

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1979年 / 11卷 / 01期

关键词：

D O I：

10.1007/BF02098340

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

To explain the mechanism of hydrogenation of NO in 2 M H2SO4, the kinetics of the hydrogenation of hydroxylamine to ammonia were studied. The rate constant of this reaction was compared with the ratio of rates at which NH3OH+ and NH4+ were generated by the hydrogenation of NO. Both of these products are formed from NO via parallel reactions of a common intermediate. A mechanism for the hydrogenation of NO and the shift of the catalyst of the potential is proposed. © 1979 Akadémiai Kiadó.

引用

页码：91 / 95

页数：5

共 5 条

[1]

HECKNER HN, 1977, J ELECTROANAL CHEM, V83, P51, DOI 10.1016/0022-0728(77)90005-5

[2] REDUCTION OF NITRIC-OXIDE AT A PLATINUM CATHODE IN AN ACIDIC SOLUTION [J].