ISOLATION AND CHARACTERIZATION OF BIS(ETA-METHYLCYCLOPENTADIENYL)DIHALOTITANIUM(IV)

被引:12
作者
CHANDRA, K [1 ]
SHARMA, RK [1 ]
GARG, BS [1 ]
SINGH, RP [1 ]
机构
[1] UNIV DELHI,DEPT CHEM,DELHI 110007,INDIA
关键词
D O I
10.1016/S0020-1693(00)95529-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
(η-MeC5H4)2TiX2 9X = Br, I) have been prepared by the raction of appropriate boron trihalides on(ηMeC5H4)2TiCl2. Improvements have been suggested over the know methods for preparing (η-MeC5H4)2TiCl2 and (η-MeC5H4)2TiX2 (X = Cl, Br, I) have also been prepared by an exchange reaction of haloacids on (η-MeC5H4)2TiF2. The complexes have been characterized by elemetal analysis, conductivity measurements, i.r. and 1H n.m.r. spectroscopy. © 1979.
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页码:125 / 127
页数:3
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