ELECTROSYNTHESIS OF (TRIFLUOROMETHYL)COPPER-COMPLEXES FROM BROMOTRIFLUOROMETHANE - REACTIVITIES WITH VARIOUS ORGANIC HALIDES

被引：22

作者：

PARATIAN, JM

LABBE, E

SIBILLE, S

PERICHON, J

机构：

[1] Laboratoire d'Electrochimie, Catalyse et Synthèse Organique, CNRS, 94320 Thiais

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 489卷 / 1-2期

关键词：

COPPER; TRIFLUOROMETHYL DERIVATIVES; ELECTROREDUCTION; MECHANISM; BROMOTRIFLUOROMETHANE; (TRIFLUOROMETHYL)COPPER COMPLEXES;

D O I：

10.1016/0022-328X(94)05154-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of (trifluoromethyl)copper complexes is achieved easily by electroreduction of bromotrifluoromethane in N,N-dimethylformamide, in the presence of a sacrificial copper anode and various potential ligands. Three (trifluoromethyl)copper species are considered: two copper(II) and one copper(I). The mechanism of formation of the (trifluoromethyl)copper species is discussed and a study of their reactivities towards various organic halides is reported.

引用

页码：137 / 143

页数：7

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