TRICARBONYL[ETA(5)-1,2,3,4,5-PENTAKIS(PROPYN-1-YL)CYCLOPENTADIENYL]-MANGANESE

被引：57

作者：

BUNZ, UHF

ENKELMANN, V

RADER, J

机构：

[1] Max-Planck-Institut für Polymerforschung, 55021 Mainz

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 12期

关键词：

D O I：

10.1021/om00036a012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound tricarbonyl[eta5-1,2,3,4,5-pentakis(propyn-1-yl)cyclopentadienyl]manganese (1b) was prepared in two steps from tricarbonylcyclopentadienylmanganese. The key step involves a 5-fold Stille coupling of tricarbonyl(eta5-1,2,3,4,5-pentaiodocyclopentadienyl)manganese with 1-(trimethylstannyl)prop-1-yne.

引用

页码：4745 / 4747

页数：3

共 30 条

[1] THE CROSS-COUPLING REACTIONS OF ORGANIC HALIDES WITH ORGANIC DERIVATIVES OF TIN, MERCURY AND COPPER CATALYZED BY PALLADIUM
BELETSKAYA, IP
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 250 (01) : 551 - 564
[2] BOESE P, 1992, ANGEW CHEM INT EDIT, V31, P1643
[3] BOEV VI, 1977, ZH OBSHCH KHIM+, V47, P727
[4] ETHYNYLFERROCENES BY DIRECT INTRODUCTION OF ACETYLENES
BUCHMEISER, M
SCHOTTENBERGER, H
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 436 (02) : 223 - 230
[5] NEW METHODS FOR DERIVATION OF ETHYNYL-SUBSTITUTED METALLOCENES
BUCHMEISER, M
SCHOTTENBERGER, H
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 441 (03) : 457 - 464
[6] SYNTHESIS OF BIS(3,4-DIMETHYLCYCLOPENTADIENYL)ACETYLENE AND BRIDGED METALLOCENES (ETA-5-C5ME5)M[ETA-5-C5H2ME2)CC(ETA-5-C5H2ME2)]M(ETA-5-C5ME5) (M = FE, NI) DERIVED THEREFROM
BUNEL, EE
VALLE, L
JONES, NL
CARROLL, PJ
GONZALEZ, M
MUNOZ, N
MANRIQUEZ, JM
[J]. ORGANOMETALLICS, 1988, 7 (03) : 789 - 791
[7] BUNZ UHF, IN PRESS ANGEW CHEM
[8] COLLMAN JP, 1987, PRINCIPLES APPLICATI
[9] MONOSUBSTITUTED CYCLOPENTADIENYL HALF-SANDWICH TRANSITION-METAL COMPLEXES
COVILLE, NJ
DUPLOOY, KE
PICKL, W
[J]. COORDINATION CHEMISTRY REVIEWS, 1992, 116 : 1 - 267
[10] HEXAETHYNYLBENZENE
DIERCKS, R
ARMSTRONG, JC
BOESE, R
VOLLHARDT, KPC
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (03): : 268 - 269

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