THE METHYLATION OF TIN(II) CHLORIDE AND TIN(II) AMINO-ACID COMPLEXES BY METHYLCOBALAMIN

被引：9

作者：

ASHBY, JR ^{[1
]}

CRAIG, PJ ^{[1
]}

机构：

[1] CITY LEICESTER POLYTECH,DEPT CHEM,POB 143,LEICESTER LE1 9BH,ENGLAND

来源：

SCIENCE OF THE TOTAL ENVIRONMENT | 1991年 / 100卷

关键词：

D O I：

10.1016/0048-9697(91)90384-Q

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Tin(II) chloride and tin(II) amino acid complexes were methylated by methylcobalamin, under conditions of chloride ion concentrations and pH relevant to the natural environment. The methylation of tin(II) chloride was both pH and chloride dependent, but the methylation of tin(II) amino acid complexes was pH dependent only. The main identified product of all reactions was monomethyl tin, which was quantified, after hydride generation, by GC/FID and fully characterised by GC/MS.

引用

页码：337 / 346

页数：10

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