LiMo3Se3 is a highly anisotropic, pseudo-one-dimensional conductor. The conductivity is based on infinite, one-dimensional chains of [Mo3Se3](-) triangles. It is also soluble in polar solvents. When it dissolves, the chains disperse to produce an Inorganic, polymer-like solution. We have used this solubility to produce free-standing, micrometer length conducting fibers with diameters as large as 60 nm and as small as the 0.6 nm diameter of a single chain.