ASYMMETRIC SYNTHESIS OF 2-ALKYLCYCLOHEXANONES ON SOLID-PHASES

被引：58

作者：

WORSTER, PM

MCARTHUR, CR

LEZNOFF, CC

机构：

[1] York University, Department of Chemistry, Toronoto, Ontario, M3J 1P3, Downsview

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 03期

关键词：

D O I：

10.1002/anie.197902211

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric syntheses on a kind of “Synthetic enzyme” appear highly promising, as shown by the reaction sequence illustrated below: S‐2‐methyl‐and S‐2‐propycyclohexanone have each been obtained in 80% chemical yield and 95 and 60% optical yield, respectively. The chiral reagent 1 can be re‐used. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：221 / 222

页数：2

共 14 条

[1] ASYMMETRIC CATALYTIC REDUCTION WITH TRANSITION-METAL COMPLEXES .2. ASYMMETRIC CATALYSIS BY A SUPPORTED CHIRAL RHODIUM COMPLEX [J].