FLUOROPHOSPHINE LIGANDS .7. DIFLUOROPHOSPHINE ADDUCTS WITH TETRABORANE-8

被引：23

作者：

CENTOFANTI, LF

KODAMA, G

PARRY, RW

机构：

[1] Department of Chemistry, University of Michigan, Ann Arbor

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 10期

关键词：

D O I：

10.1021/ic50080a008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound HF2P is a strong base toward B4H8, forming a 1:1 adduct. The adduct is significantly more stable than COB4H8 or F3PB4H8. The 11B nmr spectrum can be explained in terms of a boron cage structure similar to that found in (CH3)2NPF2B4H8. Investigation of the 19F nmr of the previously reported compound (CH3)2NPF2B4H8 suggests the existence of isomers for this compound, but no isomers were found for F2PHB4H8. © 1969, American Chemical Society. All rights reserved.

引用

页码：2072 / +

页数：1

共 7 条

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[2] CRYSTAL AND MOLECULAR STRUCTURE OF DIMETHYLAMINODIFLUOROPHOSPHINE-TETRABORANE-8, (CH3)2NPF2B4H8
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[5] FURTHER STUDIES OF TETRABORANE CARBONYL B4H8CO
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BURG, AB
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[6] DIMETHYLAMIDODIFLUOROPHOSPHINE TETRABORANE-8-F2PN(CH3)2B4H8-A STABLE ADDUCT OF B4H8
TERHAAR, G
FLEMING, MA
PARRY, RW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (09) : 1767 - &
[7] TERHAAR GL, 1962, THESIS U MICHIGAN

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