SULFONYL RADICAL-ADDITION TO NONCONJUGATED DIENES REGIOSELECTIVE AND STEREOSELECTIVE CYCLIZATIONS

被引：41

作者：

DERIGGI, I

SURZUR, JM

BERTRAND, MP

ARCHAVLIS, A

FAURE, R

机构：

[1] FAC SCI & TECH ST JEROME,CNRS 109,CHIM ORGAN LAB B,AVE ESCADRILLE NORMANDIE NIEMEN,F-13397 MARSEILLE 13,FRANCE

[2] FAC SCI & TECH ST JEROME,ESCM,F-13397 MARSEILLE 13,FRANCE

[3] FAC SCI & TECH ST JEROME,CNRS,CHIM ORGAN PHYS LAB 126,F-13397 MARSEILLE 13,FRANCE

来源：

TETRAHEDRON | 1990年 / 46卷 / 15期

关键词：

D O I：

10.1016/S0040-4020(01)87835-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Addition of TsBr to diallyl malonates and allyl methallyl malonates is described. These cyclization reactions exhibit high stereoselectivity and very high regioselectivity. The structure of the reaction products is elucidated using 2D NMR. © 1990.

引用

页码：5285 / 5294

页数：10

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