SYNTHESIS OF AZAZIRCONACYCLOPROPANES AND AZAZIRCONACYCLOPENTENES FROM ETA-2-IMINOSILAACYL COMPLEXES

被引：29

作者：

HONDA, T

SATOH, S

MORI, M

机构：

[1] HOKKAIDO UNIV,FAC PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN

[2] YAMANOUCHI PHARMACEUT CO LTD,INST DRUG DISCOVERY RES,TSUKUBA,IBARAKI 305,JAPAN

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 04期

关键词：

D O I：

10.1021/om00004a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of zirconium-silyl complex 1, which was prepared from Cp(2)ZrCl(2) and LiSi(t)BuPh(2) in THF, with isonitriles 2 gave eta(2)-iminosilaacyl complexes 3 by a one-pot procedure in good to moderate yields. Treatment of complex 3a with metal hydride and then addition of alkyne gave azazirconacyclopentene 11 via azazirconacyclopropane 7. Hydrolysis of azazirconacyclopentenes 11 gave (alpha-silylallyl)amine 10.

引用

页码：1548 / 1550

页数：3

共 11 条

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