NONHEME IRON CENTERS IN OXYGEN ACTIVATION - CHARACTERIZATION OF AN IRON(III) HYDROPEROXIDE INTERMEDIATE

被引：242

作者：

LUBBEN, M

MEETSMA, A

WILKINSON, EC

FERINGA, B

QUE, L

机构：

[1] UNIV GRONINGEN,DEPT ORGAN & MOLEC INORGAN CHEM,GRONINGEN CTR CATALYSIS & SYNTH,9747 AG GRONINGEN,NETHERLANDS

[2] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 13-14期

关键词：

ELECTROSPRAY MASS SPECTROMETRY; HYDROPEROXIDE COMPOUNDS; NONHEME IRON COMPOUNDS; OXYGEN ACTIVATION;

D O I：

10.1002/anie.199515121

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new pentadentate nitrogen ligand facilitates the synthesis of a low‐spin iron(II) complex, which reacts with H2O2 at low temperature to form the transient purple complex 1. Complex 1 was formulated as an FeIIIOOH complex, the first synthetic example of such a species to be characterized by electrospray ionization mass spectrometry. Furthermore, 1 oxidizes cyclohexane efficiently, thus supporting the notion that an FeIIIOOH moiety can participate in oxygen activation mechanisms of nonheme iron enzymes. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1512 / 1514

页数：3

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