IN-4(C(SIME(3))(3))(4) WITH IN-4-TETRAHEDRON AND IN4SE4(C(SIME(3))(3))(4) WITH IN4SE4-HETEROCUBANE STRUCTURE

被引：113

作者：

UHL, W

GRAUPNER, R

LAYH, M

SCHUTZ, U

机构：

[1] Fachbereich Chemie der Universität, D-26111 Oldenburg

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 493卷 / 1-2期

关键词：

INDIUM; TETRAHEDRON; X-RAY STRUCTURE; CLUSTER; SELENIUM; HETEROCUBANE;

D O I：

10.1016/0022-328X(95)05399-A

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of (InBr)-Br-I with LiC(SiMe(3))(3) . 2THF yields the In(I) alkyl In-4{C(SiMe(3))(3)}(4) 1 in 70% yield. 1 was characterized by a crystal structure determination showing a nearly undistorted In, tetrahedron with mean In-In distances of 300.2(1) pm. Reaction of 1 with elemental Se gives In4Se4{C(SiMe(3))(3)}(4) 2 with a slightly distorted In4Se4 hetero cubane structure.

引用

页码：C1 / C5

页数：5

共 41 条

[1] Ahlrichs R., 1993, ANGEW CHEM, V105, P1491
[2] THE PROPERTIES AND STRUCTURES OF TRIS(BENZENETHIOLATO)INDIUM(III)-BIS-PYRIDINE ADDUCT, AND OF TRIS(BENZENESELENOLATO)INDIUM(III)
ANNAN, TA
KUMAR, R
MABROUK, HE
TUCK, DG
CHADHA, RK
[J]. POLYHEDRON, 1989, 8 (07) : 865 - 871
[3] LOW OXIDATION-STATE GALLIUM COMPOUNDS - SYNTHESIS AND CHARACTERIZATION OF [GA(CH2CME3)]N
BEACHLEY, OT
PAZIK, JC
NOBLE, MJ
[J]. ORGANOMETALLICS, 1994, 13 (07) : 2885 - 2889
[4] AN ORGANOINDIUM COMPOUND CONTAINING AN INDIUM SELENIUM BOND - SYNTHESIS, PROPERTIES, AND MOLECULAR-STRUCTURE OF [ME3CCH2)2INSEPH]2
BEACHLEY, OT
LEE, JC
GYSLING, HJ
CHAO, SHL
CHURCHILL, MR
LAKE, CH
[J]. ORGANOMETALLICS, 1992, 11 (09) : 3144 - 3148
[5] SYNTHESIS, CHARACTERIZATION, AND MOLECULAR-STRUCTURE OF A COMPOUND WITH A RING OF GROUP-13, GROUP-15, AND GROUP-16 ATOMS, (ME3CCH2)2INP(T-BU)2IN(CH2CME3)2SEPH
BEACHLEY, OT
CHAO, SHL
CHURCHILL, MR
LAKE, CH
[J]. ORGANOMETALLICS, 1993, 12 (12) : 5025 - 5028
[6] SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF IN(C5ME5) - AN APPARENT OCTAHEDRAL CLUSTER
BEACHLEY, OT
CHURCHILL, MR
FETTINGER, JC
PAZIK, JC
VICTORIANO, L
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (15) : 4666 - 4668
[7] SYNTHESIS, CHARACTERIZATION, AND STRUCTURAL STUDIES OF IN(C5H4ME) BY X-RAY-DIFFRACTION AND ELECTRON-DIFFRACTION TECHNIQUES AND A REINVESTIGATION OF THE CRYSTALLINE STATE OF IN(C5H5) BY X-RAY-DIFFRACTION STUDIES
BEACHLEY, OT
PAZIK, JC
GLASSMAN, TE
CHURCHILL, MR
FETTINGER, JC
BLOM, R
[J]. ORGANOMETALLICS, 1988, 7 (05) : 1051 - 1059
[8] K21-DELTA-NA2+DELTA-IN39 (DELTA=2.8) - A CLUSTER-REPLACEMENT CLATHRATE-II STRUCTURE WITH AN ALKALI-METAL M(136)-NETWORK
CARRILLOCABRERA, W
CAROCACANALES, N
VONSCHNERING, HG
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (02): : 247 - 257
[9] Cowley A. H., 1990, INORG SYN, V27, P235
[10] POLYSELENIDE CHEMISTRY OF INDIUM AND THALLIUM IN DIMETHYLFORMAMIDE, ACETONITRILE, AND WATER - SYNTHESES, STRUCTURES, AND PROPERTIES OF THE NEW COMPLEXES [IN2(SE4)4(SE5)]4-, [IN2SE2(SE4)2]2-, [IN3SE3(SE4)3]3-, AND [TL3SE3(SE4)3]3-
DHINGRA, SS
KANATZIDIS, MG
[J]. INORGANIC CHEMISTRY, 1993, 32 (08) : 1350 - 1362

← 1 2 3 4 5 →