RAMAN-SPECTROSCOPY OF SILVER PLATING FROM A CYANIDE ELECTROLYTE

被引:18
作者
LACCONI, G [1 ]
REENTS, B [1 ]
PLIETH, W [1 ]
机构
[1] UNIV NACL CORDOBA,FAC CS QUIM,DPTO FISICOQUIM,RA-5016 CORDOBA,ARGENTINA
来源
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1992年 / 325卷 / 1-2期
关键词
D O I
10.1016/0022-0728(92)80113-I
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The electrodeposition of silver from a cyanide electrolyte is followed by surface-enhanced in-situ Raman spectroscopy (SERS) using the SERS signals of the CN vibrations in, the 2000-2150 cm-1 range. The SER spectra are generated by electrodeposition processes without anodic activation. The intensity of the SERS line reflects the microstructure of the silver surface.
引用
收藏
页码:207 / 217
页数:11
相关论文
共 15 条
[1]   Granulation, Phase Change, and Microstructure - Kinetics of Phase Change. III [J].
Avrami, M .
JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (02) :177-184
[2]   Kinetics of phase change I - General theory [J].
Avrami, M .
JOURNAL OF CHEMICAL PHYSICS, 1939, 7 (12) :1103-1112
[3]  
Avrami M., 1940, J CHEM PHYS, V8, P212, DOI DOI 10.1063/1.1750631
[4]   ELECTROCHEMICAL PHASE FORMATION (ECPF) AND MACRO-GROWTH .1. HEMISPHERICAL MODELS [J].
BOSCO, E ;
RANGARAJAN, SK .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 134 (02) :213-224
[5]  
DUFFY JI, 1981, ELECTROPLATING TECHN
[6]  
Fleischman M., 1974, CHEM PHYS LETT, V26, P123
[7]  
FLEISCHMANN M, 1986, ELECTROCHIM ACTA, V31, P900
[8]  
HILLS GJ, 1974, ELECTROCHIM ACTA, V19, P6547
[9]  
Lowenheim F.A., 1978, ELECTROPLATING
[10]   SURFACE ENHANCED RAMAN-SCATTERING OF CYANIDE CHEMISORPTION LAYERS ON SILVER ELECTROLYTE INTERFACES .2. [J].
PLIETH, W ;
ROY, B ;
BRUCKNER, H .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1982, 86 (04) :273-276