FOOTPRINT CATALYSIS .11. MOLECULAR FOOTPRINT CAVITIES IMPRINTED WITH CHIRAL AMINES AND THEIR CHIRAL MOLECULAR RECOGNITION

被引：33

作者：

MORIHARA, K

TAKIGUCHI, M

SHIMADA, T

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 04期

关键词：

D O I：

10.1246/bcsj.67.1078

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral amines, (R)- and (S)-N-benzyl-alpha-methylbenzylamine, served as templates in a molecular imprinting we developed. They formed ''molecular footprint'' cavities on a silica (alumina) gel surface, which showed catalytic activities toward transacylation of benzoic anhydride. The catalyses were susceptible to enantioselective inhibitions by the rebinding of the chiral template amines. This finding proved that the cavities could show chiral recognition through their chirally marked cavity structures.

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页码：1078 / 1084

页数：7

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