DIASTEREOSELECTIVE REACTIONS OF DELTA-SILOXYALLYLZIRCONIUM REAGENTS WITH ALDEHYDES

被引：6

作者：

CLARK, AJ

KASUJEE, I

PEACOCK, JL

机构：

[1] Department of Chemistry, University of Warwick, Coventry

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 39期

关键词：

D O I：

10.1016/0040-4039(95)01418-H

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

delta-Siloxyallylzirconium reagent (2) was produced by reaction of the TBDMS protected derivative (6) with zirconocene butene complex ''Cp(2)Zr''. Treatment of the delta-siloxyallylzirconium reagent (2) with various aldehydes provided predominantly anti-homoallylic alcohols

引用

页码：7137 / 7140

页数：4

共 18 条

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