APPLICATION OF LABILE PHOSPHORUS YLIDES IN SUGAR CHEMISTRY .2. EFFECT OF METHYLTHIOMETHYLENE-TRIPHENYLPHOSPHORANE ON ALDEHYDE SUGARS

被引：16

作者：

TRONCHET, JM

THORNDAH.SJ

BAEHLER, B

机构：

[1] Institut de chimie pharmaceutique, Université Genève, 1205

来源：

HELVETICA CHIMICA ACTA | 1969年 / 52卷 / 03期

关键词：

D O I：

10.1002/hlca.19690520333

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The action of methylthiomethylene‐triphenylphosphorane on 2,3: 4,5‐di‐O‐isopropylidene‐Aldehydo‐‐L‐arabinose led with good yield to the corresponding unsaturated sugar which underwent electrophilic addition with a high regiospecificity. This provides a useful new route for a one‐carbon chain extension in the carbohydrate series. Copyright © 1969 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：817 / &

共 10 条

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