KINETICS AND MECHANISM OF LIGAND SUBSTITUTION-REACTIONS OF RUCL3NOL2 COMPLEXES

被引：10

作者：

INNORTA, G

FOFFANI, A

TORRONI, S

SERRAZANETTI, G

机构：

[1] Istituto Chimico 'G. Ciamician', University of Bologna

来源：

INORGANICA CHIMICA ACTA | 1979年 / 35卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)93438-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A kinetic and mechanistic study on the ligand substitution reactions of RuCl3NOL2 (L = AsPh3 or SbPh3) complexes is reported. These reactions proceed via a dissociative step. The competition of different ligands for the intermediate RuCl3NOL has been investigated; steric effects seem to influence the ability of the ligands to attack this pentacoordinated intermediate. © 1979.

引用

页码：189 / 196

页数：8

共 13 条

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