CHEMICAL IONIZATION (METHANE) MASS-SPECTROMETRY OF SUGARS AND THEIR DERIVATIVES

被引：6

作者：

HEDIN, PA

PHILLIPS, VA

机构：

[1] Crop Science Research Laboratory, Agricultural Research Service, U.S. Department of Agriculture, Mississippi State

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 1991年 / 39卷 / 06期

关键词：

D O I：

10.1021/jf00006a021

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

Chemical ionization mass spectrometry (CI-MS) is an effective tool for the identification of sugars and their derivatives, often component parts of natural products. By use of methane as the reagent gas, several classes of sugars including aldoses, fructoses, di- and polysaccharides, deoxy sugars, alcohols, acids, lactones, amines, amides, and glycosides were investigated. The [MH]+ ion was generally present along with a pattern of fragmentation ions that could be used to deduce the structures.

引用

页码：1106 / 1109

页数：4

共 8 条

[1]

BUDZIKIEWICZ H, 1964, STRUCTURE ELUCIDATIO, V2, P203

[2] AMMONIA-ISOBUTANE CHEMICAL IONIZATION MASS-SPECTRA OF OLIGOSACCHARIDE PERACETATES [J].

DOUGHERTY, RC ;

ROBERTS, JD ;

BINKLEY, WW ;

CHIZHOV, OS ;

KADENTSE, VI ;

SOLOVYOV, AA .

JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (04) :451-455

[3] CHEMICAL IONIZATION MASS SPECTROMETRY OF COMPLEX MOLECULES [J].

FALES, HM ;

MILNE, GWA ;

VESTAL, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (13) :3682-&

[4]

HARRISON AG, 1983, CHEM IONIZATION MASS, P119

[5] ANALYSIS OF SUGAR DERIVATIVES BY CHEMICAL-IONIZATION MASS-SPECTROMETRY [J].

HORTON, D ;

WANDER, JD ;

FOLTZ, RL .

CARBOHYDRATE RESEARCH, 1974, 36 (01) :75-96

[6]

RADFORD T, 1980, BIOCH APPLICATIONS S, V1, pCH12

[7]

WAAGE SK, 1985, J MISS ACAD SCI, V30, P59

[8]

1983, MERCK INDEX

← 1 →