N,N'-DIMETHOXY-N,N'-DIMETHYLETHANEDIAMIDE - A USEFUL ALPHA-OXO-N-METHOXY-N-METHYLAMIDE AND 1,2-DIKETONE SYNTHON

被引：30

作者：

SIBI, MP

SHARMA, R

PAULSON, KL

机构：

[1] Department of Chemistry North Dakota State University, Fargo

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 15期

关键词：

D O I：

10.1016/0040-4039(92)88108-H

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N,N'-Dimethoxy-N,N'-dimethylethanediamide on treatment with one to two equivalents of alkyl, aryl, and benzyl Grignard reagents provide alpha-oxo-N-methoxy-N-methylamides in good to excellent yields and on reaction with excess aryllithiums furnish moderate to good yields of symmetrical 1,2-diarylketones.

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页码：1941 / 1944

页数：4

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