STEREOCHEMISTRY OF THE RUBOTTOM OXIDATION WITH BICYCLIC SILYL ENOL ETHERS - SYNTHESIS AND DIMERIZATION REACTIONS OF BICYCLIC ALPHA-HYDROXY KETONES

被引：13

作者：

JAUCH, J

机构：

[1] Institut für Organische Chemie der Universität Tübingen, D-72076 Tübingen

来源：

TETRAHEDRON | 1994年 / 50卷 / 45期

关键词：

RUBOTTOM OXIDATION; STEREOCHEMISTRY; SILYL ENOL ETHERS; ALPHA-HYDROXY KETONES; ALPHA-ACYLOXY KETONES;

D O I：

10.1016/S0040-4020(01)81209-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A modified and improved procedure for the Rubottom oxidation of bicyclic silyl enol ethers is described. The stereochemical outcome of this reaction is studied.

引用

页码：12903 / 12912

页数：10

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