DIASTEREOSELECTIVE ADDITION OF 2-TRIMETHYLSILYLOXYFURAN TO (S)-(+)-2-(P-TOLYLSULFINYL)-1,4-BENZOQUINONE

被引：22

作者：

BRIMBLE, MA

DUNCALF, LJ

REID, DCW

机构：

[1] UNIV AUCKLAND,DEPT CHEM,AUCKLAND,NEW ZEALAND

[2] MASSEY UNIV,DEPT CHEM & BIOCHEM,PALMERSTON NORTH,NEW ZEALAND

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 01期

关键词：

D O I：

10.1016/0957-4166(94)00383-M

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The uncatalyzed addition of 2-trimethylsilyloxyfuran to (S)-(+)-2-(p-tolysulfinyl)-1,4-benzoquinone 1 afforded a3.4:1 ratio of the diastereomeric adducts 2:3. Acetonitrile was found to be the optimum solvent whilst the use of Lewis acid catalysts afforded lower overall yields.

引用

页码：263 / 269

页数：7

共 27 条

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