EXTENSION OF DEBYE-HUCKEL THEORY OF ELECTROLYTE SOLUTIONS

被引：66

作者：

OUTHWAIT.CW

机构：

[1] Department of Applied Mathematics and Computing Science, University of Sheffield, Sheffield

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 50卷 / 06期

关键词：

D O I：

10.1063/1.1671378

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Debye-Hückel theory of electrolyte solutions is extended to take account of the so-called fluctuation potential. An oscillation in the Debye-Hückel potential for symmetrical electrolytes is predicted at approximately κa= 1.495 and the corresponding oscillation in the mean potential of the double layer pointed out. A simple derivation of the oscillation predicted by Kirkwood and Poirier is also given. Copyright ©1969 by the American Institute of Physics.

引用

页码：2277 / &

共 36 条

[1]

BELL GM, 1966, CHEM PHYSICS IONIC S, P409

[2]

BELL GM, 1967, 1966 C STAT MECH INT

[3] ON THE FREE ENERGY OF A MIXTURE OF IONS - AN EXTENSION OF KRAMERS THEORY [J].