SOME RELATIONS FOR VAPOR-LIQUID EQUILIBRIA AND CRITICAL MIXTURES

被引：2

作者：

REDLICH, O

MISSEN, RW

机构：

[1] Inorganic Materials Research Division, Lawrence Radiation Laboratory, Department of Chemical Engineering, University of California, Berkeley

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS | 1969年 / 8卷 / 04期

关键词：

D O I：

10.1021/i160032a021

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Several relations for vapor-liquid equilibria, partly well-known, are reviewed. The values of several derivatives for the critical point and the critical condensation point of a mixture are discussed. The critical condition (δP/δV)T = 0 can be generalized for the critical point of a binary mixture to (dP/dV)T, sat = 0, but the second derivative (d2P/dV2)T, sat is zero only for an azeotropic-critical mixture. © 1969, American Chemical Society. All rights reserved.

引用

页码：730 / &

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