SPIROANNULATION BY THE [2,3]SIGMATROPIC REARRANGEMENT VIA THE CYCLIC ALLYLSULFONIUM YLIDE - A STEREOSELECTIVE SYNTHESIS OF (+)-ACORENONE-B

被引：32

作者：

KIDO, F

ABIKO, T

KATO, M

机构：

[1] Institute for Chemical Reaction Science, Tohoku University, Katahira, Aoba-ku

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 02期

关键词：

D O I：

10.1039/p19920000229

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A spiroannulation reaction using the [2,3]sigmatropic rearrangement via a cyclic allylsulfonium ylide was developed and applied to the synthesis of (+)-acorenone B starting from (-)-perillaldehyde.

引用

页码：229 / 233

页数：5

共 28 条

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