NEW ELECTRONIC-TRANSITIONS OBSERVED IN THE TRINUCLEAR IRON(III,III,II) CLUSTER, BY INELASTIC NEUTRON-SCATTERING

被引：6

作者：

CANNON, RD

JAYASOORIYA, UA

WHITE, RP

ARAPKOSKE, SK

机构：

[1] School of Chemical Sciences, University of East Anglia, Norwich

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1993年 / 49卷 / 12期

关键词：

D O I：

10.1016/0584-8539(93)80247-8

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The incoherent inelastic neutron scattering (IINS) spectrum of the iron (III, III, II) complex [Fe3O(OOCMe)6(py)3](py) shows a pair of magnetic transitions at 199 and 221 cm-1. These are assigned to an exchange-coupled doublet, originating from the transition \S, S(ab)] = \1, 1] --> \2, 2], which from previous IINS spectra were predicted to occur at 209 cm-1.

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页码：1787 / 1791

页数：5

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