REACTIONS OF CHLOROSILANES WITH DIOXOMOLYBDENUM(VI) COMPLEXES

被引：10

作者：

ARZOUMANIAN, H

KRENTZIEN, H

CORAO, C

LOPEZ, R

AGRIFOGLIO, G

机构：

[1] CENT UNIV VENEZUELA,INST CIENCIAS TIERRA,CARACAS,VENEZUELA

[2] UNIV SIMON BOLIVAR,CARACAS 1086A,VENEZUELA

[3] CENT UNIV VENEZUELA,FAC INGN,CARACAS,VENEZUELA

来源：

POLYHEDRON | 1995年 / 14卷 / 20-21期

关键词：

D O I：

10.1016/0277-5387(95)00217-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Various trialkylchlorosilanes were reacted with a number of molybdenum-oxo complexes in order to establish the main factors which influence the process of addition of the Si-Cl function across the Mo=O bond. A novel intermolecular mode of hexaalkyldisiloxane formation was observed in one case.

引用

页码：2887 / 2891

页数：5

共 19 条

[1]

ARZOUMANIAN H, 1981, J CHEM SOC CHEM COMM, P1039

[2]

BOTTOMLEY F, 1988, ADV ORGANOMET CHEM, V88, P339

[3] PREPARATION AND MOLECULAR-STRUCTURE OF OXODIHALOGENOBIS(DIALKYLDITHIOCARBAMATO)MOLYBDENUM(VI) COMPLEXES [J].