FULLY REGIOSELECTIVE CATALYTIC CARBONYLATION OF ACRYLIC DERIVATIVES - SYNTHESIS OF METHYLMALONIC ACID BY IRON PENTACARBONYL CATALYZED HYDROCARBOXYLATION OF ACRYLIC-ACID

被引：17

作者：

BRUNET, JJ ^{[1
]}

PASSELAIGUE, E ^{[1
]}

机构：

[1] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 06期

关键词：

D O I：

10.1021/om00156a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The catalytic, fully regioselective hydrocarboxylation of acrylic acid to methylmalonic acid is reported for the first time. This reaction, which involves Fe(CO)5 as catalyst precursor in the presence of Ca(OH)2 in a H2O-IPrOH mixture as solvent, is brought about at 70 °C under atmospheric carbon monoxide pressure. © 1990, American Chemical Society. All rights reserved.

引用

页码：1711 / 1713

页数：3

共 22 条

[1] A FACILE, ONE-STEP, STEREOSELECTIVE SYNTHESIS OF NORBORNANE-2-CARBOXALDEHYDE
BRUNET, JJ
KINDELA, FB
NEIBECKER, D
[J]. SYNTHETIC COMMUNICATIONS, 1989, 19 (11-12) : 1923 - 1928
[2] SELECTIVE, IRON PENTACARBONYL CATALYZED REDUCTION OF ARYL IODIDES UNDER MILD CONDITIONS
BRUNET, JJ
TAILLEFER, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 348 (01) : C5 - C8
[3] BIMETALLIC CATALYSIS - A NEW METHOD FOR CARBONYLATION OF ARYL IODIDES UNDER MILD CONDITIONS
BRUNET, JJ
TAILLEFER, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 361 (01) : C1 - C4
[4] THE REACTION OF POTASSIUM TETRACARBONYLHYDRIDOFERRATE WITH ETHYL ACRYLATE IN ETHANOL
BRUNET, JJ
PASSELAIGUE, E
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 375 (02) : 203 - 215
[5] EXPEDIENT SYNTHESIS OF (PH3P)2FE(CO)3
BRUNET, JJ
KINDELA, FB
NEIBECKER, D
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 368 (02) : 209 - 212
[6] BIMETALLIC CATALYSIS - SYNTHESIS OF BENZOPHENONES THROUGH CARBONYLATION OF ARYL IODIDES CATALYZED BY FE(CO)5-CO2(CO)8 SYSTEMS
BRUNET, JJ
TAILLEFER, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 384 (1-2) : 193 - 197
[7] BRUNET JJ, UNPUB
[8] SYNTHETIC AND MECHANISTIC STUDIES OF REDUCTION OF ALPHA, BETA-UNSATURATED CARBONYL-COMPOUNDS BY BINUCLEAR CLUSTER, NAHFE2(CO)8
COLLMAN, JP
FINKE, RG
MATLOCK, PL
WAHREN, R
KOMOTO, RG
BRAUMAN, JI
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (04) : 1119 - 1140
[9] EISENBRAUN EJ, 1970, J CHEM EDUC, P710
[10] Falbe J., 1980, NEW SYNTHESES CARBON

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