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1,3-DIPOLAR CYCLOREVERSIONS

被引：88
作者：
BIANCHI, G [1 ]
DEMICHELI, C [1 ]
GANDOLFI, R [1 ]
机构：
[1] UNIV MILANO,IST CHIM FARMACEUT & TOSSICOL,I-20100 MILANO,ITALY
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 10期
关键词：
Cycloreversion; Dipolar cycloreversion;
D O I：
10.1002/anie.197907211
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The 1,3‐dipolar cycloreversion reaction represents a general scheme of fragmentation of pentaatomic heterocycles to produce 1,3‐dipolar systems and dipolarophiles. This review summarize cycloreversions which give rise to octet‐stabilized 1,3‐dipoles. The reaction can be either thermal or photochemical or electron impact induced. The aim of the article is to survey the published results, to emphasize the synthetic potential of this reaction, and to stimulate the study of its several not yet unambiguously defined mechanistic aspects. Copyright © 1979 by Verlag Chemie, GmbH, Germany
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收藏
页码：721 / 738
页数：18
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