ORGANOMETALLIC AMMINE COMPLEXES - THE PREPARATION AND X-RAY CRYSTAL-STRUCTURES OF [(ETA-5-C5H5)RU(PPH3)2(NH3)]PF6 AND [(ETA-5-C5H5)RU(PPH3)(CNTBU)(NH3)]PF6

被引：12

作者：

CONROYLEWIS, FM ^{[1
]}

SIMPSON, SJ ^{[1
]}

机构：

[1] UNIV SALFORD, DEPT CHEM & APPL CHEM, SALFORD M5 4WT, LANCS, ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 396卷 / 01期

关键词：

D O I：

10.1016/0022-328X(90)85195-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the neutral chloro-complexes [(η5-C5H5)Ru(PPh3)2Cl] (1) and [(η5-C5H5)Ru(PPh3)(CNtBu)Cl] (2) with ammonium hexafluorophosphate gives the ammonia cations [(η5-C5H5)Ru(PPh3)2(NH3)]PF6 (3) and [(η5-C5H5)Ru(PPh3)-(CNtBu)(NH3)]PF6 (4). The crystal structures of 3 and 4 have been determined, and the 15NH3 isotopomers prepared to facilitate spectroscopic studies. The nature of the product from the reaction of 1 and NH4F in the presence of a halide ion trap has been established. © 1990.

引用

页码：83 / 94

页数：12

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