NEW ROUTES TO COPPER-LANTHANOID COMPLEXES .1. VIA A METALLOMACROCYCLE

被引:75
作者
BLAKE, AJ [1 ]
GOULD, RO [1 ]
MILNE, PEY [1 ]
WINPENNY, REP [1 ]
机构
[1] UNIV EDINBURGH,DEPT CHEM,W MAINS RD,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND
关键词
D O I
10.1039/c39910001453
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the synthesis and structure of a novel hexanuclear copper complex of the anion of 6-methyl-2-hydroxypyridine (MeL), which undergoes reaction with lanthanum nitrate to give [La8Cu12(OH)24(NO3)22(MeLH)13(H2O)6][NO3]2[MeLH]2.CH2Cl2, a copper-lanthanoid complex with several unique structural features.
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收藏
页码:1453 / 1455
页数:3
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