SYNTHESIS AND MOLECULAR-STRUCTURE OF CD9(OC2H4OME)18,2HOC2H4OME, THE 1ST CADMIUM AGGREGATE BASED ON OXYGEN DONOR LIGANDS

被引：29

作者：

BOULMAAZ, S

PAPIERNIK, R

HUBERTPFALZGRAF, LG

VAISSERMANN, J

DARAN, JC

机构：

[1] UNIV NICE SOPHIA ANTIPOLIS,CHIM MOLEC LAB,CNRS,BP 71,F-06108 NICE 2,FRANCE

[2] CNRS,CHIM MET TRANSIT LAB,F-75230 PARIS 05,FRANCE

来源：

POLYHEDRON | 1992年 / 11卷 / 11期

关键词：

D O I：

10.1016/S0277-5387(00)83362-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The alcoholysis reactions between Cd[N(SiMe3)2]2 and functional alcohols such as 2-methoxyethanol produced soluble cadmium alkoxides. Cd9(OC2H4OMe)18, 2HOC2H4OMe has been characterized by X-ray diffraction. The compound corresponds to a centrosymmetric compact aggregate of nine cadmium atoms, the metals being hexa- or pseudo-hexa-coordinated. The alcohol molecules are hydrogen bonded to the terminal alkoxide groups. Cd-113 NMR established that the Cd9 cluster was retained in solution.

引用

收藏

页码：1331 / 1336

页数：6

相关论文

共 23 条

[1] BIMETALLIC ALKOXIDES OF ZINC AND ALUMINUM [J].

AGGRAWAL, M ;

MEHROTRA, RC .

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1988, 18 (01) :9-19

[2]

Alcock N.W., 1972, ADV INORG CHEM RAD, V15, P1, DOI DOI 10.1016/S0065-2792(08)60016-3

[3] CADMIUM SUBSTITUTION IN YBA2CU3O7-DELTA AND BI2SR2CACU2O8+DELTA [J].

ANDREAS, MT ;

KINGON, AI .

CHEMISTRY OF MATERIALS, 1991, 3 (03) :428-431

[4] DARSTELLUNG UND SCHWINKUNGSSPEKTREN VON SILYLAMIDEN DER ELEMENTE ZINK CADMIUM UND QUECKSILBER [J].

BURGER, H ;

SAWODNY, W ;

WANNAGAT, U .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1965, 3 (02) :113-&

[5] CD-113 FOURIER-TRANSFORM NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY [J].

CARDIN, AD ;

ELLIS, PD ;

ODOM, JD ;

HOWARD, JW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (07) :1672-1679

[6] AN OCTANUCLEAR CD-SN-(MU-4-O)2 COMPLEX WITH BRIDGING ACETATE AND NEOPENTOXIDE GROUPS - [CD4SN4(MU-4-O)2(O2CME)10(OCH2BUT)10] [J].

CHANDLER, C ;

FALLON, GD ;

WEST, BO .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (15) :1063-1064

[7] A NEW 3-DIMENSIONALLY NONMOLECULAR CD-S LATTICE IN CRYSTALLINE CD7(SC6H4CH3-2)14(DMF)2 [J].

DANCE, IG ;

GARBUTT, RG ;

SCUDDER, ML .

INORGANIC CHEMISTRY, 1990, 29 (08) :1571-1575

[8]

DARAN JC, 1991, CHEM MATER, V3, P779

[9] THE 1ST SQUARE-PLANAR COMPLEX OF CD(II) - CD(OAR)2(THF)2 WHERE OAR = 2,6-DI-TERT-BUTYLPHENOXIDE - A STRUCTURE GOVERNED BY 2 STRONG COVALENT AND 2 WEAK DATIVE BONDS [J].

GOEL, SC ;

CHIANG, MY ;

BUHRO, WE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (18) :6724-6725

[10] A VERY LARGE CALCIUM DIALKOXIDE MOLECULAR AGGREGATE HAVING A CDI2 CORE GEOMETRY - CA9(OCH2CH2OME)18(HOCH2CH2OME)2 [J].

GOEL, SC ;

MATCHETT, MA ;

CHIANG, MY ;

BUHRO, WE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (05) :1844-1845